I purchased a 1/350 scale Enterprise NX-01 from Polar Lights off of eBay and received it this afternoon. Before that, I was reading up on a lot of posts on various forums about problems people were having with painting this model, namely the paint lifting after applying Aztec Dummy's mask.
I'm just going to give you a quick rundown of what I've accomplished so far. Questions will follow.
I washed all of the pieces using warm water and liquid dish soap. I let them dry thoroughly and then applied a gray primer (Model Masters). I did a misting coat and then applied a heavier coat around an hour later. I already ran into my first slight problem: despite my best efforts, the spray can occasionally spewed out tiny blobs of paint, which left some chunks on my model. I'm hoping that I can sand those out once the paint dries. They're not big by any means, but unfortunately I'm a perfectionist (I'm the kind of guy who uses a magnifying glass to look for grains of cat hair stuck in the paint) so the tiniest flaw bothers me immensely.
It seems that Testor's Metalizers are popular for starships such as this. I don't have an airbrush so I want to buy spray cans for as much as I can... namely Aluminum, Steel, and Gunmetal. I still need to find something similar to Titanium Gold. However, all the spray can versions need to be buffed... and I don't want to buff.

While on the subject of the Metalizer series, some people have reported having problems with the paint lifting when removing Aztec Dummy's paint mask, even after applying a sealant. I plan on buying this mask so I want to be prepared.
I'm very new to the advanced methods of modeling, so my questions are:
1. Should I wait a week to allow the primer (enamel) to fully cure before applying my base coat?
2. Since I plan on using Aztec Dummy's mask, I need a durable enamel that won't lift, no matter what! :-) Hearing "there's a 50/50 chance of this paint lifting" won't cut it for me. Any step-by-step techniques would be most appreciated!
3. What colors have people used on this model? I'm having trouble finding a Titanium Gold enamel in spray can form. Is there anything else that will match very closely?
4. I was leaning on the Metalizers series for a very long time. Is the buffing required? Keep in mind I don't want the model to shine like glass. I'm just worried about the paint lifting.
I'd very much like to hear back from someone who has built this model and used Aztec Dummy's mask. Thank you ahead of time for reading this rather long post and answering any questions that you can! I’m sure you’ll be hearing a lot from me these next two months. :-)